Huan Liu, Da Yang, Dong-Liang Wang, Peng Wang, Yong Lu, VO-Thanh Giang and Ye Liu
Chem. Commun., 2018,54, 7979-7982
DOI:
10.1039/C8CC03431A,
Communication
Hydroaminomethylation of olefins with H2O as the hydrogen source was accomplished over an Ir-catalyst with the involvement of an ionic diphosphine (L6). The use of H2O as the hydrogen source could completely inhibit the hydrogenation of olefins. The π-accepting ability and improved stability of L6 endowed the corresponding Ir-catalyst with high activity and good longevity for recycling uses.