Issue 41, 2014

How to interpret Onsager cross terms in mixed ionic electronic conductors

Abstract

The interpretation of Onsager cross transport coefficients measured in mixed ionic electronic conductor (MIEC) oxides is examined. It is demonstrated that the cross terms are an artifact of the way the measurements are analyzed. When an appropriate, comprehensive defect model is considered for the MIEC, no cross terms are required.

Graphical abstract: How to interpret Onsager cross terms in mixed ionic electronic conductors

Associated articles

Article information

Article type
Paper
Submitted
17 Jul 2014
Accepted
09 Sep 2014
First published
09 Sep 2014

Phys. Chem. Chem. Phys., 2014,16, 22513-22516

Author version available

How to interpret Onsager cross terms in mixed ionic electronic conductors

I. Riess, Phys. Chem. Chem. Phys., 2014, 16, 22513 DOI: 10.1039/C4CP03154G

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