Issue 11, 2019

Rh(i)-Catalyzed intramolecular [3 + 2] cycloaddition reactions of yne-vinylidenecyclopropanes

Abstract

A cationic Rh(I) complex-catalyzed intramolecular [3 + 2] cycloaddition reaction of newly developed yne-vinylidenecyclopropanes (VDCPs) has been established, affording an efficient synthesis of fused [6.5]-bicyclic structures in moderate to good yields under mild conditions. Moreover, the reaction exhibits a broad substrate scope along with good functional group tolerance.

Graphical abstract: Rh(i)-Catalyzed intramolecular [3 + 2] cycloaddition reactions of yne-vinylidenecyclopropanes

Supplementary files

Article information

Article type
Research Article
Submitted
08 Mär 2019
Accepted
02 Apr 2019
First published
03 Apr 2019

Org. Chem. Front., 2019,6, 1816-1820

Rh(I)-Catalyzed intramolecular [3 + 2] cycloaddition reactions of yne-vinylidenecyclopropanes

K. Rui and M. Shi, Org. Chem. Front., 2019, 6, 1816 DOI: 10.1039/C9QO00343F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements