Issue 21, 2011

Linking [FeIII3] triangles with “double-headed”phenolic oximes

Abstract

The use of “double-headed” phenolic oximes produces a trigonal antiprismatic [FeIII3]2 cluster with an “internal cavity” filled with an additional Fe3+ ion. Magnetic measurements reveal that the competition between different exchange interactions leads to a low-spin ground multiplet weakly separated in energy from a complex pattern of low-lying excited levels.

Graphical abstract: Linking [FeIII3] triangles with “double-headed”phenolic oximes

Supplementary files

Article information

Article type
Communication
Submitted
25 Feb 2011
Accepted
24 Mär 2011
First published
11 Apr 2011

Chem. Commun., 2011,47, 6018-6020

Linking [FeIII3] triangles with “double-headed”phenolic oximes

K. Mason, J. Chang, E. Garlatti, A. Prescimone, S. Yoshii, H. Nojiri, J. Schnack, P. A. Tasker, S. Carretta and E. K. Brechin, Chem. Commun., 2011, 47, 6018 DOI: 10.1039/C1CC11146A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements