An organic–inorganic hybrid supramolecular framework material based on a [P2W18O62]6− cluster and Yb & Na complexes of pyridine-2,6-dicarboxylic acid: a catalyst for selective oxidation of sulfides in water with H2O2

Pulikanti Guruprasad Reddy; Narsimha Mamidi; Chullikkattil P. Pradeep

doi:10.1039/C5CE02546J

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An organic–inorganic hybrid supramolecular framework material based on a [P₂W₁₈O₆₂]⁶⁻ cluster and Yb & Na complexes of pyridine-2,6-dicarboxylic acid: a catalyst for selective oxidation of sulfides in water with H₂O₂†

Pulikanti Guruprasad Reddy,^a Narsimha Mamidi

^a and Chullikkattil P. Pradeep*^a

Author affiliations

* Corresponding authors

^a School of Basic Sciences, Indian Institute of Technology Mandi, Mandi 175001, Himachal Pradesh, India
E-mail: pradeep@iitmandi.ac.in
Fax: +91 1905 267 009

Abstract

A rare-earth-containing polyoxometalate (RECP) hybrid, {(Yb (PDCH₂)₂(PDCH))·Na(H₂O)₂·(Na(PDCH)(H₂O)₂)}₂[P₂W₁₈O₆₂]·14H₂O (1), based on [P₂W₁₈O₆₂]⁶⁻ cluster anions and cationic Yb & Na complex units of pyridine-2,6-dicarboxylic acid (PDCH₂) has been synthesized under normal reaction conditions, which exhibited a supramolecular 3-D framework structure in the crystal lattice. Hybrid 1 acts as a green catalyst for the selective oxidation of sulfides in water with H₂O₂ as the reagent.

This article is part of the themed collection: 2016 New talent

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Article information

DOI: https://doi.org/10.1039/C5CE02546J
Article type: Communication
Submitted: 24 dec 2015
Accepted: 04 mar 2016
First published: 07 mar 2016

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CrystEngComm, 2016,18, 4272-4276

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An organic–inorganic hybrid supramolecular framework material based on a [P₂W₁₈O₆₂]⁶⁻ cluster and Yb & Na complexes of pyridine-2,6-dicarboxylic acid: a catalyst for selective oxidation of sulfides in water with H₂O₂

P. G. Reddy, N. Mamidi and C. P. Pradeep, CrystEngComm, 2016, 18, 4272 DOI: 10.1039/C5CE02546J

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