Themed collection Special Issue: Frontiers of Hydrogen Energy and Fuel Cells

19 items
Open Access Editorial

Introduction to the themed issue on frontiers of hydrogen energy and fuel cells

Guest editors Lior Elbaz, Minhua Shao, Jianglan Shui and Carlo Santoro introduce the Industrial Chemistry & Materials themed issue on hydrogen energy and fuel cells.

Graphical abstract: Introduction to the themed issue on frontiers of hydrogen energy and fuel cells
Open Access Perspective

Ammonia as a carbon-free hydrogen carrier for fuel cells: a perspective

The potential of utilizing ammonia as a hydrogen carrier for on-site power generation via ammonia decomposition is systematically discussed.

Graphical abstract: Ammonia as a carbon-free hydrogen carrier for fuel cells: a perspective
Open Access Minireview

Recent progress in high-loading single-atom catalysts and their applications

Achieving single-atom dispersion of metal active components remains daunting. Here, we summarized several key synthesis methods and applications of high-loading SACs, hoping to highlight important research areas for future development.

Graphical abstract: Recent progress in high-loading single-atom catalysts and their applications
Open Access Minireview

Cutting-edge methods for amplifying the oxygen evolution reaction during seawater electrolysis: a brief synopsis

Three approaches for enhancing OER activity and selectivity for hydrogen production in seawater electrolysis.

Graphical abstract: Cutting-edge methods for amplifying the oxygen evolution reaction during seawater electrolysis: a brief synopsis
Open Access Minireview

Designing active and stable Ir-based catalysts for the acidic oxygen evolution reaction

Various strategies for optimization of Ir-based OER catalysts are summarized, including elemental doping, surface engineering, atomic utilization and support engineering.

Graphical abstract: Designing active and stable Ir-based catalysts for the acidic oxygen evolution reaction
Open Access Minireview

Core–shell nanostructured magnesium-based hydrogen storage materials: a critical review

This minireview focuses on the synthesis of core–shell nanostructured magnesium-based materials to achieve hydrogen storage performances and analyses the mechanistic effects of this unique structure.

Graphical abstract: Core–shell nanostructured magnesium-based hydrogen storage materials: a critical review
Open Access Review Article

Recent progress of antipoisoning catalytic materials for high temperature proton exchange membrane fuel cells doped with phosphoric acid

The current challenges and opportunities faced by HT-PEMFCs are discussed, as well as possible future solutions. This review can provide guidance for the future development of high-performance HT-PEMFC catalysts.

Graphical abstract: Recent progress of antipoisoning catalytic materials for high temperature proton exchange membrane fuel cells doped with phosphoric acid
Open Access Review Article

Recent progress of manganese dioxide based electrocatalysts for the oxygen evolution reaction

This review discusses the OER reaction mechanism (AEM and LOM) and the research progress of MnO2-based OER catalysts. The optimization strategy of MnO2-based catalysts was summarized.

Graphical abstract: Recent progress of manganese dioxide based electrocatalysts for the oxygen evolution reaction
Open Access Review Article

Non-noble metals as activity sites for ORR catalysts in proton exchange membrane fuel cells (PEMFCs)

Proton exchange membrane fuel cells (PEMFCs) have great potential to become the next generation green energy technique, but its application is limited by the slow kinetics of the cathode oxygen reduction reaction (ORR) in acidic medium.

Graphical abstract: Non-noble metals as activity sites for ORR catalysts in proton exchange membrane fuel cells (PEMFCs)
Open Access Paper

Electrochemical impedance spectroscopy of PEM fuel cells at low hydrogen partial pressures: efficient cell tests for mass production

Electrochemical impedance spectroscopy of PEM fuel cells under varying hydrogen concentrations reveals the origins of the correlation between hydrogen partial pressure and fuel cell performance.

Graphical abstract: Electrochemical impedance spectroscopy of PEM fuel cells at low hydrogen partial pressures: efficient cell tests for mass production
Open Access Paper

Electrochemical recovery of Pt/C electrocatalyst: optimization of the potential range on the leaching process and application to an aged MEA

An optimized potential window for efficient platinum electrodissolution, the first step of a Pt recycling process, is proposed.

Graphical abstract: Electrochemical recovery of Pt/C electrocatalyst: optimization of the potential range on the leaching process and application to an aged MEA
From the themed collection: Virtual Collections—ICM HOT Papers
Open Access Paper

Effect of the calcination temperature on the characteristics of Ni/Fe-oxide electrocatalysts for application in anion exchange membrane electrolysers

Ni–Fe oxides were prepared by the oxalate pathway and heat-treated at three different temperatures. An outstanding performance was achieved in AEMWE by NiFeOx 450-anode-based MEA.

Graphical abstract: Effect of the calcination temperature on the characteristics of Ni/Fe-oxide electrocatalysts for application in anion exchange membrane electrolysers
Open Access Paper

Unveiling the particle size effect and surface reactivity of Pt/C nanoparticles for ammonia electrooxidation using in situ infrared spectroscopy

In situ PM-IRRAS provides information about the reaction products of ammonia electrooxidation on the surface of Pt/C nanoparticles and in the bulk of electrolyte.

Graphical abstract: Unveiling the particle size effect and surface reactivity of Pt/C nanoparticles for ammonia electrooxidation using in situ infrared spectroscopy
Open Access Paper

Highly active ZIF-8@CNT composite catalysts as cathode materials for anion exchange membrane fuel cells

This study investigates the oxygen reduction reaction activity of transition-metal-doped ZIF-8 and carbon-nanotube-based composite catalysts in alkaline media and their performance in anion-exchange membrane fuel cells using an Aemion+® 15 μm AEM.

Graphical abstract: Highly active ZIF-8@CNT composite catalysts as cathode materials for anion exchange membrane fuel cells
Open Access Paper

The effect of grafted alkyl side chains on the properties of poly(terphenyl piperidinium) based high temperature proton exchange membranes

New high-performance high temperature proton exchange membranes have been developed for fuel cell applications.

Graphical abstract: The effect of grafted alkyl side chains on the properties of poly(terphenyl piperidinium) based high temperature proton exchange membranes
Open Access Paper

Does the platinum-loading in proton-exchange membrane fuel cell cathodes influence the durability of the membrane-electrode assembly?

MEAs with various cathode Pt loadings were elaborated and aged using a multiple-stressor accelerated stress test (AST) in a segmented PEMFC.

Graphical abstract: Does the platinum-loading in proton-exchange membrane fuel cell cathodes influence the durability of the membrane-electrode assembly?
Open Access Paper

Investigation on electrocatalytic performance and material degradation of an N-doped graphene-MOF nanocatalyst in emulated electrochemical environments

This study presents electrochemical performance loss and correlated material degradation of an electrocatalyst, nitrogen-doped graphene integrated with a metal–organic framework (N-G/MOF), by the effect of H2O2-derived oxidative species.

Graphical abstract: Investigation on electrocatalytic performance and material degradation of an N-doped graphene-MOF nanocatalyst in emulated electrochemical environments
Open Access Paper

Mono-, bi- and tri-metallic platinum group metal-free electrocatalysts for hydrogen evolution reaction following a facile synthetic route

HER electrocatalysts were synthesized starting from metal-phthalocyanine. The higher pyrolysis temperature is beneficial and associated with the formation of nanoparticles. The addition of the second and third metal is also beneficial for HER.

Graphical abstract: Mono-, bi- and tri-metallic platinum group metal-free electrocatalysts for hydrogen evolution reaction following a facile synthetic route
Open Access Paper

Polyaniline-derived carbon nanofibers with a high graphitization degree loading ordered PtNi intermetallic nanoparticles for oxygen reduction reaction

A three-dimensional carbon nanofiber (CNF) with a high graphitization degree was fabricated via high temperature treatment of polyaniline network. The CNF-1200 used as platinum-based catalyst ORR support exhibited excellent corrosion resistance.

Graphical abstract: Polyaniline-derived carbon nanofibers with a high graphitization degree loading ordered PtNi intermetallic nanoparticles for oxygen reduction reaction
19 items

About this collection

As the most promising clean energy carrier in the 21st century, hydrogen represents the centerpiece in the transformation of energy and environmental technology. Moving toward a hydrogen-based society is crucial for humanity to address global sustainability issues and meet carbon neutrality targets, of which hydrogen production and storage, and hydrogen energy conversion (through fuel cells) are key technologies.

It is becoming increasingly clear that the development of these technologies is accelerating and interdependent. At present, demands for low-cost and at-scale chemistries and materials exist in every segment linking the hydrogen energy chain. This special issue aims to collect the inputs from the leading experts on the status, directions, and recent research breakthroughs in building future hydrogen energy ecosystem. 

We welcome contributions on hydrogen and fuel cells in the form of Research papers, Communications, Reviews and Perspectives in the following but not limited to the categories:
  • Hydrogen storage materials
  • Hydrogen production and generation
  • Fuel cell materials from membranes to electrodes
  • Fuel cell catalysts

This collection is guest edited by Prof. Lior Elbaz (Bar-Ilan University, Israel), Prof. Minhua Shao (The Hong Kong University of Science and Technology, China), Prof. Jianglan Shui (Beihang University,China), Prof. Carlo Santoro (University of Milano-Bicocca, Italy,)

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