Themed collection 2023 Inorganic Chemistry Frontiers Review-type Articles

69 items
Highlight

Does it mix? Insights and attempts to predict the formability of single phase mixed A-cation lead iodide perovskites

Current data suggest that radii and N–H bonds control the solubility and phase segregation in mixed A-cation lead iodide perovskites.

Graphical abstract: Does it mix? Insights and attempts to predict the formability of single phase mixed A-cation lead iodide perovskites
From the themed collection: FOCUS: Perovskite Materials and Devices
Open Access Highlight

Electrifying synthesis of organosilicon compounds – from electrosynthesis to electrocatalysis

Organosilicon compounds via electrosynthesis – the recent developments and further challenges.

Graphical abstract: Electrifying synthesis of organosilicon compounds – from electrosynthesis to electrocatalysis
Review Article

Tin as a co-catalyst for electrocatalytic oxidation and reduction reactions

Tin (Sn) as a co-catalyst exerts a substantial influence on multiple electrocatalytic reactions. Delving into Sn's role in electrocatalysts and pioneering novel strategies have an immense impact for green synthesis and energy production.

Graphical abstract: Tin as a co-catalyst for electrocatalytic oxidation and reduction reactions
Review Article

Hydrogen storage as liquid solar fuels

This review article focuses on catalytic interconversion between hydrogen and liquid or solid solar fuels using metal complexes as redox catalysts.

Graphical abstract: Hydrogen storage as liquid solar fuels
Review Article

Highly efficient tungsten/molybdenum-based electrocatalysts for the oxygen reduction reaction: a review

The mechanisms, synthesis methods and strategies for application of W/Mo-based ORR electrocatalysts are briefly introduced. Recent advances in W/Mo-based ORR electrocatalysts are discussed in detail.

Graphical abstract: Highly efficient tungsten/molybdenum-based electrocatalysts for the oxygen reduction reaction: a review
Review Article

Organelle imaging with carbon dots: strategies, challenges, and perspectives

Organelle imaging is an efficient approach to gain information about intracellular events and dynamics of subcellular structures.

Graphical abstract: Organelle imaging with carbon dots: strategies, challenges, and perspectives
Open Access Review Article

The role of high-resolution transmission electron microscopy and aberration corrected scanning transmission electron microscopy in unraveling the structure–property relationships of Pt-based fuel cells electrocatalysts

Exploring the nanostructures of platinum-based fuel cell electrocatalysts through the lens of advanced transmission electron microscopy techniques unveils the secrets of structure-activity-stability relationships.

Graphical abstract: The role of high-resolution transmission electron microscopy and aberration corrected scanning transmission electron microscopy in unraveling the structure–property relationships of Pt-based fuel cells electrocatalysts
Review Article

The chemistry of the s- and p-block elements with 2,2′:6′,2′′-terpyridine ligands

The manifold chemistry of terpyridine (tpy) ligands with main-group elements is reviewed not only to provide an overview on this topic but to also inspire intensified research in this often disregarded field.

Graphical abstract: The chemistry of the s- and p-block elements with 2,2′:6′,2′′-terpyridine ligands
Review Article

The multiple roles of rare earth elements in the field of photocatalysis

The role and classification of rare earth elements in photocatalysts are summarized, with the aim of providing suggestions for the future development of rare earth photocatalysts.

Graphical abstract: The multiple roles of rare earth elements in the field of photocatalysis
Review Article

Local structural environment of single-atom catalysts

In this review, we discuss the catalytically active sites of single-atom catalysts regulated by modulating the metal single-atoms and coordination environment, as well as summarizing major challenges and development opportunities for the field of SACs.

Graphical abstract: Local structural environment of single-atom catalysts
Review Article

Towards scalability: progress in metal oxide charge transport layers for large-area perovskite solar cells

In this review article, we aim to offer a focused overview of metal oxide CTLs for large-area PSCs, emphasizing recent advancements in deposition techniques, modification strategies, and their suitability for large-area device applications.

Graphical abstract: Towards scalability: progress in metal oxide charge transport layers for large-area perovskite solar cells
From the themed collection: FOCUS: Perovskite Materials and Devices
Open Access Review Article

The role of niobium in layered oxide cathodes for conventional lithium-ion and solid-state batteries

This review article highlights the advantages of niobium as a dopant and a coating constituent for improving cycling performance of layered Ni-rich oxide cathodes in liquid- and solid-electrolyte-based Li-ion batteries.

Graphical abstract: The role of niobium in layered oxide cathodes for conventional lithium-ion and solid-state batteries
Review Article

Recent progress in the development of tin tungstate (α-SnWO4) photoanodes for solar water oxidation

Tin tungstate is an emerging complex oxide photoelectrode for solar water splitting. Here, recent developments in the material are thoroughly reviewed, summarizing its properties, different syntheses, limitations, modification strategies and outlook.

Graphical abstract: Recent progress in the development of tin tungstate (α-SnWO4) photoanodes for solar water oxidation
Review Article

Recent advances in electrocatalytic reduction of ambient CO2 toward high-value feedstock

The effects of climate change have arisen due to greenhouse gases emitted into the atmosphere, and the finite supply of fossil fuels will eventually be unable to support the needs of the petrochemical industry.

Graphical abstract: Recent advances in electrocatalytic reduction of ambient CO2 toward high-value feedstock
Review Article

Recent advances towards increasing the Pt utilization efficiency for hydrogen evolution reaction: a review

Pt, an ideal HER catalyst, is costly, hindering its use in wide-scale applications. Here, we discuss how advances to Pt alloys, heterostructures, and SACs improve Pt atomic utilization for HER, and how spectator ions and pH affect performance.

Graphical abstract: Recent advances towards increasing the Pt utilization efficiency for hydrogen evolution reaction: a review
Review Article

Advances in research on the inhibitory effect of 3D current collector structures for lithium dendrites

The structural advantages and disadvantages of various 3D current collectors are summarized to provide suggestions for the future development of anode in lithium metal batteries.

Graphical abstract: Advances in research on the inhibitory effect of 3D current collector structures for lithium dendrites
Review Article

Abiotic transformations of nitrogen mediated by iron sulfides and related species from early Earth to catalyst design

In this review, we aim to systematically investigate the interaction of nitrogen species with iron sulfides and related materials, with the goal of understanding how abiotic processes may have contributed to the evolution of enzymes responsible for nitrogen transformations.

Graphical abstract: Abiotic transformations of nitrogen mediated by iron sulfides and related species from early Earth to catalyst design
From the themed collection: Nitrogen-cycle electrocatalysis
Review Article

The importance of second sphere interactions on single molecule magnet performance

Secondary interactions occur beyond the primary coordination sphere and can influence the performance of single molecule magnets (SMMs). This article highlights the role that secondary interactions play in the synthesis and performance of SMMs.

Graphical abstract: The importance of second sphere interactions on single molecule magnet performance
Review Article

Current progress in metal–organic frameworks and their derivatives for electrocatalytic water splitting

For electrocatalytic water splitting, MOFs can be optimized through structural modification, plane design and synergetic composite systems, and the annealing process further expands the types of MOF-based electrocatalytic materials.

Graphical abstract: Current progress in metal–organic frameworks and their derivatives for electrocatalytic water splitting
Review Article

Investigating the role of oxygen vacancies in metal oxide for enhanced electrochemical reduction of NO3 to NH3: mechanistic insights

Ammonia (NH3) is a crucial chemical commodity used extensively in fertilizer production and as a renewable potential energy carrier.

Graphical abstract: Investigating the role of oxygen vacancies in metal oxide for enhanced electrochemical reduction of NO3− to NH3: mechanistic insights
From the themed collection: Nitrogen-cycle electrocatalysis
Review Article

Molecular inspired electrocatalyst materials for environmental remediation

The increasing presence of chemical contaminants in the environment due to demands associated with a growing population and industrial development poses risks to human health due to their exposure.

Graphical abstract: Molecular inspired electrocatalyst materials for environmental remediation
Open Access Review Article

Challenges and advancement in direct ammonia solid oxide fuel cells: a review

This review discusses the challenges and recent advancements in direct ammonia solid oxide fuel cells for electricity generation in a single step to pave the way for developing kilowatt-scale technology and offering future recommendations.

Graphical abstract: Challenges and advancement in direct ammonia solid oxide fuel cells: a review
Review Article

Recent progress in gas separation platforms based on hydrogen-bonded organic frameworks (HOFs)

Hydrogen-bonded frameworks (HOFs) are a new and appealing class of porous crystalline materials that are constructed from organic moieties through hydrogen bonding.

Graphical abstract: Recent progress in gas separation platforms based on hydrogen-bonded organic frameworks (HOFs)
Review Article

Latest progress in proton-conducting hydrogen-bonded organic frameworks

The latest progress of proton-conductive HOFs in terms of preparation, structural characteristics, proton conductivity, and proton-conducting mechanism are presented. The future trends and design ideas are also highlighted and prospected.

Graphical abstract: Latest progress in proton-conducting hydrogen-bonded organic frameworks
Review Article

Designing Janus catalysts for renewable energy-relevant bifunctional small molecule activation

Developing bifunctional catalysts is critical for ensuring renewable energy applications via small molecule activation.

Graphical abstract: Designing Janus catalysts for renewable energy-relevant bifunctional small molecule activation
Review Article

Recent advances of metal oxide catalysts for electrochemical NH3 production from nitrogen-containing sources

This article summarizes recent advances in metal oxides catalyzed ammonia production via the electrocatalysis of N2 and nitrates. Critical challenges and future research directions to accomplish their potential industrialization are discussed.

Graphical abstract: Recent advances of metal oxide catalysts for electrochemical NH3 production from nitrogen-containing sources
Review Article

Recent progress and prospects of rare earth elements for advanced aqueous zinc batteries

We analyze the unique roles played by rare earth elements from the three perspectives of cathode, anode and electrolyte. We summarize their potential applications and rational optimization strategies towards electrodes, separators and electrolytes.

Graphical abstract: Recent progress and prospects of rare earth elements for advanced aqueous zinc batteries
Review Article

Porous framework materials for stable Zn anodes in aqueous zinc-ion batteries

This review summarizes the recent research efforts on MOFs/COFs employed in Zn anodes of zinc-ion batteries (ZIBs) and analyzes the structure-property relationship to guide the rational design of MOFs/COFs for future ZIB applications.

Graphical abstract: Porous framework materials for stable Zn anodes in aqueous zinc-ion batteries
Review Article

Recent advances in molybdenum diselenide-based electrocatalysts: preparation and application in the hydrogen evolution reaction

This review summarizes the preparation of MoSe2-based materials, their application in hydrogen evolution reaction (HER), the catalytic mechanism for improved HER performance, structure–performance correlations and the challenges in the future.

Graphical abstract: Recent advances in molybdenum diselenide-based electrocatalysts: preparation and application in the hydrogen evolution reaction
Open Access Review Article

An overview of Mg-based IR nonlinear optical materials

This review article provides an overview of Mg-based IR nonlinear optical materials including synthetic methods, structural chemistry, structure–activity relationships, current problems and future development.

Graphical abstract: An overview of Mg-based IR nonlinear optical materials
Review Article

Single-ion magnetism behaviors in lanthanide(III) based coordination frameworks

Incorporating Ln(III) ions into coordination framework structures confers multifunctional properties such as single-ion magnetism, host–guest interactions, and more, which could have broad applications in diverse fields.

Graphical abstract: Single-ion magnetism behaviors in lanthanide(iii) based coordination frameworks
Review Article

Recent developments and prospects for engineering first-row transition metal-based catalysts for electrocatalytic NOx reduction to ammonia

First-row transition metal-based electrocatalysts, including Cu, Fe, Co, Ni, and Ti-based electrocatalysts, for high-efficiency NOx reduction are reviewed. These electrocatalysts should possess three advantages indicated in the figure above.

Graphical abstract: Recent developments and prospects for engineering first-row transition metal-based catalysts for electrocatalytic NOx− reduction to ammonia
From the themed collection: Nitrogen-cycle electrocatalysis
Review Article

Li2ZnTi3O8 anode: design from material to electrode and devices

Li2ZnTi3O8 anode has been widely reviewed with respect to material design, electrode design, and device construction design.

Graphical abstract: Li2ZnTi3O8 anode: design from material to electrode and devices
Review Article

Recent developments in Ti-based nanocatalysts for electrochemical nitrate-to-ammonia conversion

Electrochemical NO3-to-NH3 conversion is an available option for sewage treatment and ammonia synthesis. This review summarized the theoretical insights, design strategy and challenges of Ti-based electrocatalysts for NO3-to-NH3 conversion.

Graphical abstract: Recent developments in Ti-based nanocatalysts for electrochemical nitrate-to-ammonia conversion
From the themed collection: Nitrogen-cycle electrocatalysis
Review Article

Advances in the application of manganese dioxide and its composites for theranostics

This review summarizes recent advances in the application of manganese dioxide and its composites for theranostics.

Graphical abstract: Advances in the application of manganese dioxide and its composites for theranostics
Review Article

Bimetallic-based composites for potassium-ion storage: challenges and perspectives

Bimetallic-based compounds are regarded as promising anode materials. This review highlights design strategies of various bimetallic-based compounds and summarizes the latest research progress, challenges and prospectives for their applications in PIBs.

Graphical abstract: Bimetallic-based composites for potassium-ion storage: challenges and perspectives
Review Article

Recent progress in ammonia synthesis based on photoelectrocatalysis

Photoelectrocatalytic NH3 synthesis from N2 and H2O is a promising approach for N-neutralization goal based on catalytic strategies, such as vacancy engineering, ion doping, frustrated Lewis pair design, heterojunction construction, etc.

Graphical abstract: Recent progress in ammonia synthesis based on photoelectrocatalysis
From the themed collection: Nitrogen-cycle electrocatalysis
Review Article

Recent advances and strategies of electrocatalysts for large current density industrial hydrogen evolution reaction

The urgent demand for sustainable energy resources has boosted research into highly efficient electrocatalysts for the hydrogen evolution reaction (HER).

Graphical abstract: Recent advances and strategies of electrocatalysts for large current density industrial hydrogen evolution reaction
Open Access Review Article

Opportunities and challenges in aqueous nitrate and nitrite reduction beyond electrocatalysis

Nitrate (NO3) and nitrite (NO2) ions are common health-threatening contaminants in water. Thermal catalytic hydrogenation is a promising strategy to reduce nitrate and nitrite during water treatment.

Graphical abstract: Opportunities and challenges in aqueous nitrate and nitrite reduction beyond electrocatalysis
From the themed collection: Nitrogen-cycle electrocatalysis
Review Article

Research progress of MXenes and layered double hydroxides for supercapacitors

In this study, the preparation methods of MXenes and layered dihydroxides (LDHs) are reviewed. In addition, the preparation and the electrochemical performances for supercapacitors of MXene/LDHs composites are summarized in detail.

Graphical abstract: Research progress of MXenes and layered double hydroxides for supercapacitors
Review Article

N-heterocyclic carbene-ligated metal complexes and clusters for photocatalytic CO2 reduction

N-heterocyclic carbenes are structurally versatile ligands, which have strong σ-donor properties to form covalent bonds with metal centers. This frontier article provides a review on active NHC-stabilized metal complexes and clusters for photocatalytic CO2 reduction.

Graphical abstract: N-heterocyclic carbene-ligated metal complexes and clusters for photocatalytic CO2 reduction
Review Article

Magnetic materials based on heterometallic CrII/III–LnIII complexes

Exchange interaction plays a pivotal role in dictating the single-molecule magnet (SMM) behaviour in heterometallic complexes. This review covers SMM and magnetocaloric effects of Cr(III)–Ln(III)-based heterometallic complexes.

Graphical abstract: Magnetic materials based on heterometallic CrII/III–LnIII complexes
Review Article

Microbial biosynthesis of quantum dots: regulation and application

The production of quantum dots by microorganisms is regulated by both intracellular and extracellular factors. Gaining a better understanding of the regulatory mechanism will facilitate the precise modulation of their properties.

Graphical abstract: Microbial biosynthesis of quantum dots: regulation and application
Review Article

Halide perovskite photovoltaic-electrocatalysis for solar fuel generation

This review covers the principles and recent advances in photovoltaic-electrochemical fuel production. It suggests the structural, compositional, and interfacial engineering of OER, HER, bifunctional, CRR catalysts, and halide perovskite solar cells.

Graphical abstract: Halide perovskite photovoltaic-electrocatalysis for solar fuel generation
From the themed collection: FOCUS: Perovskite Materials and Devices
Review Article

Emerging heterostructured C3N4 photocatalysts for photocatalytic environmental pollutant elimination and sterilization

Photocatalysis is deemed a highly prominent technology to solve environmental problems such as pollution, CO2 emission and bacterial contamination.

Graphical abstract: Emerging heterostructured C3N4 photocatalysts for photocatalytic environmental pollutant elimination and sterilization
Review Article

Actinide-based single-molecule magnets: alone or in a group?

This review presents a survey of representative mononuclear and multinuclear actinide SMMs to look back at how far we have come, trying to seek out a feasible strategy for top-performing An-SMMs.

Graphical abstract: Actinide-based single-molecule magnets: alone or in a group?
Review Article

Strategies to boost chemiresistive sensing performance of In2O3-based gas sensors: an overview

Morphologies oriented different composite materials of In2O3-based gas sensors.

Graphical abstract: Strategies to boost chemiresistive sensing performance of In2O3-based gas sensors: an overview
Review Article

Recent progress and strategies on the design of catalysts for electrochemical ammonia synthesis from nitrate reduction

This review summarizes recent advancements in catalysts for NH3 electrosynthesis from NO3, highlights various strategies to regulate their apparent or intrinsic activities, and proposes the perspective and challenges in this emerging area.

Graphical abstract: Recent progress and strategies on the design of catalysts for electrochemical ammonia synthesis from nitrate reduction
From the themed collection: Nitrogen-cycle electrocatalysis
Review Article

Emerging trends in mesoporous silica nanoparticle-based catalysts for CO2 utilization reactions

Mesoporous silica nanoparticles (MSNs) have modifiable porous surfaces, can be easily modified/functionalized, and have good chemical/thermal stability; thus, they are promising candidates in the field of CO2 conversion/reduction reactions.

Graphical abstract: Emerging trends in mesoporous silica nanoparticle-based catalysts for CO2 utilization reactions
Review Article

Selective ethylene tetramerization: an overview

1-octene is used to produce linear low-density polyethylene (LLDPE), polyolefin elastomers (POE) etc. This review provides an overview of the history, recent advancements and future opportunities in selective ethylene tetramerization.

Graphical abstract: Selective ethylene tetramerization: an overview
Review Article

Development and perspectives of multi-site electrocatalysts for neutral hydrogen evolution

This review offers an overview of the design principles, progress, and perspectives of applying multi-site electrocatalysts for the HER in neutral media.

Graphical abstract: Development and perspectives of multi-site electrocatalysts for neutral hydrogen evolution
Review Article

A comprehensive review of carbon anode materials for potassium-ion batteries based on specific optimization strategies

This review mainly focuses on the discussion of mechanisms behind improved potassium storage properties, starting from some specific optimization strategies, and presents a perspective for the further development of carbon anodes.

Graphical abstract: A comprehensive review of carbon anode materials for potassium-ion batteries based on specific optimization strategies
Open Access Review Article

Mechanisms of Mg carbonates precipitation and implications for CO2 capture and utilization/storage

The precipitation of anhydrous Mg carbonates is hindered by the high energy barrier for dehydrating Mg2+ cations, and the mechanisms involved (classical or non-classical crystallization) in their precipitation remains as a scientific gap.

Graphical abstract: Mechanisms of Mg carbonates precipitation and implications for CO2 capture and utilization/storage
Open Access Review Article

Diruthenium(II,III) paddlewheel complexes: effects of bridging and axial ligands on anticancer properties

Diruthenium(II,III) paddlewheel carboxylates combine the pharmacological properties of the dimetallic center with those ascribed to the μ-bridged carboxylates, thus leading to novel, dual-acting anticancer metallodrugs.

Graphical abstract: Diruthenium(ii,iii) paddlewheel complexes: effects of bridging and axial ligands on anticancer properties
Review Article

Recent progress in polyoxometalate–viologen photochromic hybrids: structural design, photochromic mechanism, and applications

Polyoxometalate–viologen hybrids are reviewed, including structural design, competing electron transfer process, and new knowledge on photochromic mechanisms and their applications.

Graphical abstract: Recent progress in polyoxometalate–viologen photochromic hybrids: structural design, photochromic mechanism, and applications
Review Article

Prospect of Ru(edta) complexes in nitrogen cycle electrocatalysis: a mini review

This mini review chronicles the role of Ru(edta) (edta4− = ethylenediaminetetraacetate) towards catalysing the electrochemical transformation of nitrogen cycle reactions, elucidating the complex mechanistic schemes.

Graphical abstract: Prospect of Ru(edta) complexes in nitrogen cycle electrocatalysis: a mini review
From the themed collection: Nitrogen-cycle electrocatalysis
Review Article

Latest progress in asymmetrically functionalized Anderson-type polyoxometalates

Asymmetrically functionalized Anderson-type polyoxometalates were overviewed, including the key factors of various synthesis methods, separation methods, advantages of asymmetric structures, and their applications.

Graphical abstract: Latest progress in asymmetrically functionalized Anderson-type polyoxometalates
From the themed collection: FOCUS: Metal and Metal-Containing Clusters
Review Article

Recent developments of core–shell structured catalysts for the selective catalytic reduction of NOx with ammonia

Recent developments in syntheses strategies, catalytic performance as well as structure–property relationships of core–shell structured catalysts for NH3-SCR of NOx with improved low-temperature activity and poisoning tolerance is surveyed.

Graphical abstract: Recent developments of core–shell structured catalysts for the selective catalytic reduction of NOx with ammonia
Review Article

Recent advances in surface reconstruction toward self-adaptive electrocatalysis: a review

Self-adaptive electrocatalysis of inorganic materials was proposed and its origin, basic principles, and recent advances were discussed toward the fabrication of self-adaptive cycles for sustainable electrocatalysis.

Graphical abstract: Recent advances in surface reconstruction toward self-adaptive electrocatalysis: a review
Review Article

Electrode/electrolyte additives for practical sodium-ion batteries: a mini review

Problems of practical sodium-ion batteries.

Graphical abstract: Electrode/electrolyte additives for practical sodium-ion batteries: a mini review
Review Article

Regulation strategy of white emission from organic–inorganic hybrid metal halide perovskites

In this review, the structure, photophysical properties, and white-light mechanism of organic–inorganic hybrid metal halide perovskites with white emission are summarized, with an emphasis on the adjustment strategy for white-light performance.

Graphical abstract: Regulation strategy of white emission from organic–inorganic hybrid metal halide perovskites
Research Article

Distinct electronic effects of borane– and boryl–nickel complexes for catalyzing H2 activation

Electrophilic borane and nucleophilic boryl transition metal catalysts for H2 activation.

Graphical abstract: Distinct electronic effects of borane– and boryl–nickel complexes for catalyzing H2 activation
Open Access Chemistry Frontiers

Group 14 metallole dianions as η5-coordinating ligands

The coordination chemistry of group 14 metallole dianions, compared to monoanionic cyclopentadienides, is underexplored. This perspective reviews η5-coordination in group 14 metallole dianions, revealing their potential in organometallic chemistry.

Graphical abstract: Group 14 metallole dianions as η5-coordinating ligands
Chemistry Frontiers

Single-atom nanozymes as promising catalysts for biosensing and biomedical applications

Single-atom nanozymes represent a unique class of enzyme mimics that exhibit maximal atomic utilization, a well-defined electronic/geometric structure, and high catalytic activity, and have found diverse applications in biomedicine and biosensing.

Graphical abstract: Single-atom nanozymes as promising catalysts for biosensing and biomedical applications
Chemistry Frontiers

Nanoarchitectonics for inorganic chemistry frontiers

This short article discusses nanoarchitectonics as a frontier in inorganic chemistry as exemplified by high entropy alloys, quasi-subnanometer-sized particles, probe-manipulated nanomaterials, and interfacial-processed nanofilms.

Graphical abstract: Nanoarchitectonics for inorganic chemistry frontiers
Chemistry Frontiers

Parsing the basic principles to build efficient heterostructures toward electrocatalysis

This Chemistry Frontiers article systematically parses the inherent principles of universal component selection strategies, catalytic mechanisms, and structure–activity relationships for novel heterostructural electrocatalysts.

Graphical abstract: Parsing the basic principles to build efficient heterostructures toward electrocatalysis
Chemistry Frontiers

The trianionic hydrazido radical (N2)3−: a promising platform for transforming N2

A quintessential approach to activate and functionalize the exceptionally stable diatomic nitrogen (N2) consists of its coordination to transition metal complexes.

Graphical abstract: The trianionic hydrazido radical (N2)3−: a promising platform for transforming N2
Chemistry Frontiers

The art of compartment design for synthetic catalysts

Compartmentalization of catalysts has potential to become a powerful synthetic tool, however, further work in understanding its fundamental principles is required. Herein, those principles are elucidated through the lens of biomimicry.

Graphical abstract: The art of compartment design for synthetic catalysts
Open Access Chemistry Frontiers

Transition-metal phosphors with emission peak maximum on and beyond the visible spectral boundaries

Third-row transition-metal complexes displaying efficient true-blue (∼460–470 nm) and near infrared (∼700–1000 nm) emissions were strategically analyzed.

Graphical abstract: Transition-metal phosphors with emission peak maximum on and beyond the visible spectral boundaries
69 items

About this collection

Critical reviews, highlights and chemistry frontiers articles published in Inorganic Chemistry Frontiers during 2023 are collated as below for the benefit of readers.

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