Issue 36, 2022

Being negative can be positive: metal oxide anions promise more selective methane to methanol conversion

Abstract

Computational studies are performed to show that metal oxide anionic complexes promote the CH4 + N2O → CH3OH + N2 reaction with low activation barriers for the C–H activation and the formation of the CH3–OH bond. The energy for the release of the produced methanol is minimal, reducing the residence time of methanol around the catalytic center and preventing its overoxidation.

Graphical abstract: Being negative can be positive: metal oxide anions promise more selective methane to methanol conversion

Supplementary files

Article information

Article type
Communication
Submitted
18 জুন 2022
Accepted
06 সেপ্টে. 2022
First published
07 সেপ্টে. 2022

Phys. Chem. Chem. Phys., 2022,24, 21583-21587

Being negative can be positive: metal oxide anions promise more selective methane to methanol conversion

S. Sader and E. Miliordos, Phys. Chem. Chem. Phys., 2022, 24, 21583 DOI: 10.1039/D2CP02771B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements