Chiral expression of adsorbed (MP) 5-amino[6]helicenes: from random structures to dense racemic crystals by surface alloying

Javier D. Fuhr; Maarten W. van der Meijden; Lucila J. Cristina; Luis M. Rodríguez; Richard M. Kellogg; J. Esteban Gayone; Hugo Ascolani; Magalí Lingenfelder

doi:10.1039/C6CC06785A

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Chiral expression of adsorbed (MP) 5-amino[6]helicenes: from random structures to dense racemic crystals by surface alloying†

Javier D. Fuhr,*^a Maarten W. van der Meijden,^b Lucila J. Cristina,‡^a Luis M. Rodríguez,^a Richard M. Kellogg,^b J. Esteban Gayone,^a Hugo Ascolani*^a and Magalí Lingenfelder

*^c

Author affiliations

* Corresponding authors

^a Centro Atómico Bariloche, Avda. E. Bustillo 9500, R8402AGP, Bariloche, Argentina
E-mail: ascolani@cab.cnea.gov.ar, fuhr@cab.cnea.gov.ar

^b Syncom BV, Kadijk 3, 9747 AT Groningen, The Netherlands

^c Max Planck-EPFL Laboratory for Molecular Nanoscience, EPFL SB CMNT NL-CMNT, CH 1015 Lausanne, Switzerland
E-mail: magali.lingenfelder@epfl.ch

Abstract

The chiral expression of a molecule on a surface is driven from a random solid solution on Cu(100) to a racemic crystal on a Sn/Cu(100) alloy. Density functional theory simulations reveal how the growth of the racemate is influenced by the underlying surface.

This article is part of the themed collections: Celebrating Excellence in Research: 100 Women of Chemistry and Chirality at the nanoscale

Download options Please wait...

Supplementary files

Supplementary information PDF (1729K)

Article information

DOI: https://doi.org/10.1039/C6CC06785A
Article type: Communication
Submitted: 18 авг 2016
Accepted: 29 ное 2016
First published: 29 ное 2016

Download Citation

Chem. Commun., 2017,53, 130-133

Permissions

Request permissions

Chiral expression of adsorbed (MP) 5-amino[6]helicenes: from random structures to dense racemic crystals by surface alloying

J. D. Fuhr, M. W. van der Meijden, L. J. Cristina, L. M. Rodríguez, R. M. Kellogg, J. E. Gayone, H. Ascolani and M. Lingenfelder, Chem. Commun., 2017, 53, 130 DOI: 10.1039/C6CC06785A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications

Chiral expression of adsorbed (MP) 5-amino[6]helicenes: from random structures to dense racemic crystals by surface alloying†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Chiral expression of adsorbed (MP) 5-amino[6]helicenes: from random structures to dense racemic crystals by surface alloying

Social activity

Search articles by author

Spotlight

Advertisements