Extended conjugation has been introduced into boroles but only on the 2,3- or 4,5-positions of the central BC4 core. In this work we synthesize phenanthrylboroles that also have conjugation on the 3,4-positions and demonstrate their insertion reactivity with azides to furnish B,N-analogues of pyrene.
H. Zacharias, A. Begum, J. Han, T. A. Bartholome, T. B. Marder and C. D. Martin, Chem. Commun., 2024, Accepted Manuscript , DOI: 10.1039/D4CC02863E
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