Issue 26, 2017

Dehydrogenation of cyclic amines by a coordinatively unsaturated Cp*Ir(iii) phosphoramidate complex

Abstract

The reaction of a Cp*Ir(III) phosphoramidate complex with secondary amines gives amine, imine-bound Cp*Ir(III) hydride complexes resulting from amine dehydrogenation. These well-characterized species could serve as models of relevant intermediates that have been proposed in catalytic amine dehydrogenation using related N,O-chelated Cp*Ir(III) pyridonate complexes.

Graphical abstract: Dehydrogenation of cyclic amines by a coordinatively unsaturated Cp*Ir(iii) phosphoramidate complex

Supplementary files

Article information

Article type
Paper
Submitted
25 apr 2017
Accepted
31 may 2017
First published
01 iyn 2017

Dalton Trans., 2017,46, 8621-8625

Dehydrogenation of cyclic amines by a coordinatively unsaturated Cp*Ir(III) phosphoramidate complex

M. W. Drover, L. L. Schafer and J. A. Love, Dalton Trans., 2017, 46, 8621 DOI: 10.1039/C7DT01499F

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