Issue 80, 2013

Can heterometallic 1-dimensional chains support current rectification?

Abstract

To what extent can a heterometallic chain of transition metal ions generate an asymmetric current–voltage response? Density functional theory suggests that the answer depends very much on the symmetry of the dominant conduction channel: π channels are more localised and hence afford higher rectification ratios.

Graphical abstract: Can heterometallic 1-dimensional chains support current rectification?

Supplementary files

Article information

Article type
Communication
Submitted
09 iyl 2013
Accepted
22 avq 2013
First published
22 avq 2013

Chem. Commun., 2013,49, 9116-9118

Can heterometallic 1-dimensional chains support current rectification?

D. DeBrincat, O. Keers and J. E. McGrady, Chem. Commun., 2013, 49, 9116 DOI: 10.1039/C3CC45063E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements