Issue 23, 2022

Pd/Ni-metal–organic framework-derived porous carbon nanosheets for efficient CO oxidation over a wide pH range

Abstract

Metal nanocrystal ornamented metal–organic frameworks (MOFs) are of particular interest in multidisciplinary applications; however, their electrocatalytic CO oxidation performance over wide pH ranges is not yet reported. Herein, Ni-MOF-derived hierarchical porous carbon nanosheets (Ni-MOF/PC) with abundant Ni–Nx sites decorated with Pd nanocrystals (Pd/Ni-MOF/PC) were synthesized by microwave-irradiation (MW-I) followed by annealing at 900 °C and subsequent etching of Ni-MOF/C prior to Pd deposition. The fabrication mechanism comprises the generation of self-reduced reducing gases from triethylamine during the annealing and selective chemical etching of Ni, thereby facilitating the reduction of Ni-anchored MOF and Pd nanocrystal deposition with the aid of ethylene glycol and MW-I to yield Pd/Ni–Nx enriched MOF/PC. The synthetic strategies endear the Pd/Ni-MOF/PC with unique physicochemical merits: abundant defects, interconnected pores, high electrical conductivity, high surface area, Ni-deficient but more active sites for Pd/Ni–Nx in porous carbon nanosheets, and synergism. These merits endowed the CO oxidation activity and stability on Pd/Ni-MOF/PC substantially than those of Pd/Ni-MOF/C and Pd/C catalysts in wide pH conditions (i.e., KOH, HClO4, and NaHCO3). The CO oxidation activity study reveals the utilization of MOF/PC with metal nanocrystals (Pd/Ni) in CO oxidation catalysis.

Graphical abstract: Pd/Ni-metal–organic framework-derived porous carbon nanosheets for efficient CO oxidation over a wide pH range

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Supplementary files

Article information

Article type
Paper
Submitted
15 iyl 2022
Accepted
04 sen 2022
First published
05 sen 2022
This article is Open Access
Creative Commons BY license

Nanoscale Adv., 2022,4, 5044-5055

Pd/Ni-metal–organic framework-derived porous carbon nanosheets for efficient CO oxidation over a wide pH range

A. K. Ipadeola, K. Eid, A. M. Abdullah, R. S. Al-Hajri and K. I. Ozoemena, Nanoscale Adv., 2022, 4, 5044 DOI: 10.1039/D2NA00455K

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