Issue 25, 2020

Interfacial engineering of a polymer–MOF composite by in situ vitrification

Abstract

Non-stoichoimetric crystalline ZIF-62 was used as the filler for a 6FDA-DAM polyimide-based composite membrane. In situ melting and vitrification of ZIF-62 was then performed, to yield the ZIF-62 glass phase (agZIF-62), within the polymer matrix. Focus ion beam scanning electron microscopy (FIB-SEM), thermal characterisation and membrane separation tests demonstrate the filling of voids at the MOF/polymer interface from the liquid phase of ZIF-62.

Graphical abstract: Interfacial engineering of a polymer–MOF composite by in situ vitrification

Supplementary files

Article information

Article type
Communication
Submitted
25 yan 2020
Accepted
07 mar 2020
First published
09 mar 2020

Chem. Commun., 2020,56, 3609-3612

Interfacial engineering of a polymer–MOF composite by in situ vitrification

R. Lin, J. Hou, M. Li, Z. Wang, L. Ge, S. Li, S. Smart, Z. Zhu, T. D. Bennett and V. Chen, Chem. Commun., 2020, 56, 3609 DOI: 10.1039/D0CC00664E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements