Issue 53, 2019

Switchable living nickel(ii) α-diimine catalyst for ethylene polymerisation

Abstract

Design and synthesis of a Ni(II) “sandwich” α-diimine complex (1) resulted in a switchable catalyst for the living polymerisation of ethylene over a range of temperatures and pressures. Varying these conditions produced a well-defined tetrablock copolymer comprising branched and highly linear polyethylenes. This copolymer improved the toughness of a phase separated LDPE/HDPE blend by nonreactive interfacial compatibilisation.

Graphical abstract: Switchable living nickel(ii) α-diimine catalyst for ethylene polymerisation

Supplementary files

Article information

Article type
Communication
Submitted
24 apr 2019
Accepted
28 may 2019
First published
14 iyn 2019

Chem. Commun., 2019,55, 7607-7610

Author version available

Switchable living nickel(II) α-diimine catalyst for ethylene polymerisation

O. Padilla-Vélez, K. S. O’Connor, A. M. LaPointe, S. N. MacMillan and G. W. Coates, Chem. Commun., 2019, 55, 7607 DOI: 10.1039/C9CC03154E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements