Palladium-catalyzed amino and oxyacetoxylation have been developed to furnish 1,4-benzodiazepinones and 1,4-benzoxazepinones through the diheterofunctionalization of alkenes. This study demonstrates the ability of this new methodology to allow 7-exo ring-closure.
A. D. Manick, G. Duret, D. N. Tran, F. Berhal and G. Prestat, Org. Chem. Front., 2014, 1, 1058 DOI: 10.1039/C4QO00179F
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