Issue 100, 2023

Modulation of [8]CPP properties by bridging two phenylene units

Abstract

We report the synthesis and characterization of two new fluorophores, consisting of a [8]cyclo-para-phenylene core in which two phenylenes are bridged by either a nitrogen atom or a carbonyl group. The nitrogen bridge increases the HOMO–LUMO gap, whereas the carbonyl bridge decreases it. These results provide guidelines to control the electronic properties of nanohoops.

Graphical abstract: Modulation of [8]CPP properties by bridging two phenylene units

Supplementary files

Article information

Article type
Communication
Submitted
20 ربيع الأول 1445
Accepted
08 جمادى الأولى 1445
First published
08 جمادى الأولى 1445

Chem. Commun., 2023,59, 14835-14838

Modulation of [8]CPP properties by bridging two phenylene units

D. Ari, E. Dureau, O. Jeannin, J. Rault-Berthelot, C. Poriel and C. Quinton, Chem. Commun., 2023, 59, 14835 DOI: 10.1039/D3CC04924H

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