Issue 6, 2022

[closo-B10H8-1,10-(COOH)2]2−: a building block for functional materials?

Abstract

[closo-B10H8-1,10-(COOH)2]2− was obtained in five steps and 40% overall yield from [closo-B10H10]2−. It can be converted to [closo-B10H8-1,10-(CO)2] and subsequently to carbonium ylides [closo-B10H8-1-COOH-10-(C(NRCH2)2)]. The diacid, its derivatives, and di-ylide [closo-B10H8-1,10-(C(NHMe)2)2] are characterized by spectroscopic and single crystal XRD methods augmented with DFT results.

Graphical abstract: [closo-B10H8-1,10-(COOH)2]2−: a building block for functional materials?

Supplementary files

Article information

Article type
Communication
Submitted
12 ربيع الثاني 1443
Accepted
11 جمادى الأولى 1443
First published
11 جمادى الأولى 1443

Chem. Commun., 2022,58, 851-854

Author version available

[closo-B10H8-1,10-(COOH)2]2−: a building block for functional materials?

S. Kapuściński, O. Hietsoi, A. Pietrzak, A. C. Friedli and P. Kaszyński, Chem. Commun., 2022, 58, 851 DOI: 10.1039/D1CC06485A

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