Issue 20, 2017

Dimension-controlled ion-pairing assemblies based on π-electronic charged species

Abstract

This feature article summarizes the recent progress in the study of ion-pairing assemblies based on π-electronic ion pairs, including anion complexes of π-electronic molecules. Recently, ionic self-assembly (or ion-pairing assembly) has been widely investigated and utilized in the fabrication of various functional materials including soft materials, surface morphologies and organic–inorganic hybrid materials. It is significantly important to precisely design and synthesize charged π-electronic systems for obtaining highly organized assemblies, but the development of π-electronic ion pairs with an aim to fabricate soft materials has hardly been examined. This is because in many cases it is difficult to arrange the desired charged species due to their synthetic difficulties. In view of this scenario, tailor-made π-electronic ion pairs consisting of ion complexes of π-electronic molecules and their counterions can be used as the building blocks for ion-pairing assemblies. In particular, dimension-controlled ion-pairing assemblies can be formed based on π-electronic charged species, which have potential for use as functional nanostructured materials. In this feature article, we overview the basic synthetic strategies and recent examples of ion-pairing assemblies comprising π-electronic systems.

Graphical abstract: Dimension-controlled ion-pairing assemblies based on π-electronic charged species

Article information

Article type
Feature Article
Submitted
28 ربيع الأول 1438
Accepted
04 جمادى الأولى 1438
First published
05 جمادى الأولى 1438

Chem. Commun., 2017,53, 2894-2909

Dimension-controlled ion-pairing assemblies based on π-electronic charged species

Y. Haketa and H. Maeda, Chem. Commun., 2017, 53, 2894 DOI: 10.1039/C6CC10255G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements