Issue 3, 1998
From the journal:

Chemical Communications

A metallacyclic λ5-phosphaalkenyl complex of ruthenium(II): X-ray structure of [Ru{κ2-P([double bond, length half m-dash]O)CButC([double bond, length half m-dash]O)}(CNBut)2(PPh3)2]

Anthony F. Hill,   Andrew J. P. White,   David J. Williams,   James D. E. T. Wilton-Ely,   Anthony F. Hill  and  Cameron Jones  

Abstract

The reaction of [Ru(P[double bond, length half m-dash]CHBut)Cl(CO)(PPh3)2] 1 or [Ru(P[double bond, length half m-dash]CHBut)Cl(CNBut)(CO)(PPh3)2] 2b with excess pivalo isonitrile under aerobic conditions provides the novel metallacyclic λ5-phosphaalkenyl-P complex [Ru{κ2-P([double bond, length half m-dash]O)CButC([double bond, length half m-dash]O)}(CNBut)2(PPh3)2], which has been crystallographically characterised.

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Article information

DOI
https://doi.org/10.1039/A707987G
Article type
Paper

Chem. Commun., 1998, 367-368

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A metallacyclic λ5-phosphaalkenyl complex of ruthenium(II): X-ray structure of [Ru{κ2-P([double bond, length half m-dash]O)CButC([double bond, length half m-dash]O)}(CNBut)2(PPh3)2]

A. F. Hill, A. J. P. White, D. J. Williams, J. D. E. T. Wilton-Ely, A. F. Hill and C. Jones, Chem. Commun., 1998, 367 DOI: 10.1039/A707987G

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