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Issue 12, 2014
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A metal–organic framework as a chemical guide to control hydrogen desorption pathways of ammonia borane

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Abstract

We report that ammonia borane with a high uptake capacity for hydrogen can be encapsulated in a metal–organic framework (MOF) via capillary action, where the MOF functions as a chemical guide to control the hydrogen desorption pathways of ammonia borane by releasing only pure hydrogen, lowering its hydrogen desorption temperature, and suppressing its volumetric expansion during hydrogen desorption.

Graphical abstract: A metal–organic framework as a chemical guide to control hydrogen desorption pathways of ammonia borane

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Supplementary files

Article information


Submitted
09 Mar 2014
Accepted
11 Apr 2014
First published
15 Apr 2014

Nanoscale, 2014,6, 6526-6530
Article type
Communication
Author version available

A metal–organic framework as a chemical guide to control hydrogen desorption pathways of ammonia borane

H. M. Jeong, W. H. Shin, J. H. Park, J. H. Choi and J. K. Kang, Nanoscale, 2014, 6, 6526 DOI: 10.1039/C4NR01296H

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