Pyrophosphate analogues are of great importance especially for the design of biologically active molecules. The phospha-Claisen condensation allows for the rapid synthesis of (phosphonomethyl)phosphinate pyrophosphate analogues and building blocks that can be employed in numerous applications.
F. Gelat, C. Lacomme, O. Berger, L. Gavara and J.-L. Montchamp, Org. Biomol. Chem., 2015, 13, 825 DOI: 10.1039/C4OB02007C
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