Issue 1, 2014
From the journal:

Dalton Transactions

Synthesis and characterization of an octanuclear copper(i) methanediide cluster†

Wing-Por Leung,*a   Yuk-Chi Chana  and  Thomas C. W. Maka  

* Corresponding authors

a Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong, China
E-mail: kevinleung@cuhk.edu.hk
Fax: +852 2603 5057

Abstract

The reaction of [K{CH(iPr2P[double bond, length as m-dash]S)2(C9H6N-2)}]n (1) with one equivalent of CuCl in THF afforded a rare octanuclear copper(I) methanediide cluster (3). The structure of compound 3 as determined by X-ray crystallography was found to have eight copper atoms that form a Gyrobifastigium (J26).

Graphical abstract: Synthesis and characterization of an octanuclear copper(i) methanediide cluster

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Article information

DOI
https://doi.org/10.1039/C3DT52833B
Article type
Communication
Submitted
09 Oct 2013
Accepted
17 Oct 2013
First published
18 Oct 2013

Dalton Trans., 2014,43, 63-66

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Synthesis and characterization of an octanuclear copper(I) methanediide cluster

W. Leung, Y. Chan and T. C. W. Mak, Dalton Trans., 2014, 43, 63 DOI: 10.1039/C3DT52833B

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