Issue 25, 2014
From the journal:

Chemical Communications

Direct carboxylation of allylic halides with carbon dioxide in the presence of indium†

Bukeyan Miaoa  and  Shengming Ma*ab  

* Corresponding authors

a Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry, East China Normal University, 3663 North Zhongshan Lu, Shanghai 200062, P.R. China
E-mail: masm@sioc.ac.cn
Fax: +86-21-6260-9305

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, P.R. China

Abstract

A highly regioselective indium-mediated allylation of carbon dioxide starting from simple allylic halides (X = I, Br, Cl) has been developed. No transition metal catalyst is needed and an inert atmosphere is not necessary. The reaction tolerates a wide range of synthetically attractive functional groups with a very high branched regioselectivity.

Graphical abstract: Direct carboxylation of allylic halides with carbon dioxide in the presence of indium

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Article information

DOI
https://doi.org/10.1039/C4CC00148F
Article type
Communication
Submitted
08 Jan 2014
Accepted
29 Jan 2014
First published
31 Jan 2014

Chem. Commun., 2014,50, 3285-3287

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Direct carboxylation of allylic halides with carbon dioxide in the presence of indium

B. Miao and S. Ma, Chem. Commun., 2014, 50, 3285 DOI: 10.1039/C4CC00148F

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