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Issue 25, 2014
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A cooperative water effect in proazaphosphatrane-catalysed heterocycle synthesis

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Abstract

The synthesis of oxazolines and imidazolines was achieved by activation of isocyanides with water. Mechanistic studies show that the organosuperbase proazaphosphatrane is tolerant of water within the reaction medium, with a beneficial and cooperative effect being observed.

Graphical abstract: A cooperative water effect in proazaphosphatrane-catalysed heterocycle synthesis

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Publication details

The article was received on 28 Dec 2013, accepted on 31 Jan 2014 and first published on 31 Jan 2014


Article type: Communication
DOI: 10.1039/C3CC49808E
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Citation: Chem. Commun., 2014,50, 3288-3291
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    A cooperative water effect in proazaphosphatrane-catalysed heterocycle synthesis

    M. A. Honey, Y. Yamashita and S. Kobayashi, Chem. Commun., 2014, 50, 3288
    DOI: 10.1039/C3CC49808E

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