Issue 33, 2012
From the journal:

Dalton Transactions

Organometallic derivatives of Rh- and Ir-substituted polyoxotungstates with Keggin structure: reactivity screening by electrospray ionization mass-spectrometry†

Maxim N. Sokolov,*ab   Sergey A. Adonin,ab   Pavel L. Sinkevich,b   Cristian Vicent,c   Dmitry A. Mainicheva  and  Vladimir P. Fedinab  

* Corresponding authors

a Nikolaev Institute of Inorganic Chemistry SB RAS, 630090, Lavrentieva st. 3, Novosibirsk, Russia
E-mail: caesar@niic.nsc.ru
Fax: +7 383-330-94-89
Tel: +7 383-316-58-45

b Novosibirsk State University, 63009, Pirogova st. 2, Novosibirsk, Russia

c Serveis Centrals d'Instrumentació Científica, Universitat Jaume I, Avda. Sos Baynat s/n, Castelló, Spain

Abstract

ESI-MS based methodology for the rapid reactivity screening of [PW11O39RhCl]5− and [PW11O39Ir(H2O)]4− toward various metalation-intended substrates (reagents with an activated C–H bond, boronic acids and organotin compounds) is presented. Formation of a series of new organometallic POM derivatives with Rh–R (R = malonate, phenylacetate, CH3, Ph, ferrocenyl) and Ir–R (R = CH3) bonds is reported.

Graphical abstract: Organometallic derivatives of Rh- and Ir-substituted polyoxotungstates with Keggin structure: reactivity screening by electrospray ionization mass-spectrometry

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Article information

DOI
https://doi.org/10.1039/C2DT30655G
Article type
Communication
Submitted
22 Mar 2012
Accepted
18 Jun 2012
First published
19 Jun 2012

Dalton Trans., 2012,41, 9889-9892

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Organometallic derivatives of Rh- and Ir-substituted polyoxotungstates with Keggin structure: reactivity screening by electrospray ionization mass-spectrometry

M. N. Sokolov, S. A. Adonin, P. L. Sinkevich, C. Vicent, D. A. Mainichev and V. P. Fedin, Dalton Trans., 2012, 41, 9889 DOI: 10.1039/C2DT30655G

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