Issue 33, 2012
From the journal:

Dalton Transactions

Keggin polyoxoanion supported organic–inorganic trinuclear lutetium cluster, {Na(H2O)3[Lu(pydc)(H2O)3]3}[SiW12O40]·26.5H2O†

Suzhi Li,ab   Dongdi Zhang,a   Yuan Yuan Guo,a   Pengtao Ma,a   Xiaoyang Qiu,b   Jingping Wang*a  and  Jingyang Niu*a  

* Corresponding authors

a Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, P.R. China
E-mail: jpwang@henu.edu.cn, jyniu@henu.edu.cn
Fax: (+86) 378-3886876
Tel: (+86) 378-3886876

b Department of Chemistry, Shangqiu Normal University, Shangqiu Henan 476000, P.R. China

Abstract

A novel strawberry-like organic–inorganic hybrid, {Na(H2O)3[Lu(pydc)(H2O)3]3}[SiW12O40]·26.5H2O (H2pydc = pyridine-2,6-dicarboxylate) containing an intriguing trinuclear lutetium cluster {Na(H2O)3[Lu(pydc)(H2O)3]3}4+ has been synthesized and its luminescent properties, IR, UV, TG, PXRD analyses and single crystal X-ray diffraction were investigated.

Graphical abstract: Keggin polyoxoanion supported organic–inorganic trinuclear lutetium cluster, {Na(H2O)3[Lu(pydc)(H2O)3]3}[SiW12O40]·26.5H2O

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Supplementary files

Article information

DOI
https://doi.org/10.1039/C2DT30517H
Article type
Communication
Submitted
04 Mar 2012
Accepted
21 May 2012
First published
23 May 2012

Dalton Trans., 2012,41, 9885-9888

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Keggin polyoxoanion supported organic–inorganic trinuclear lutetium cluster, {Na(H2O)3[Lu(pydc)(H2O)3]3}[SiW12O40]·26.5H2O

S. Li, D. Zhang, Y. Y. Guo, P. Ma, X. Qiu, J. Wang and J. Niu, Dalton Trans., 2012, 41, 9885 DOI: 10.1039/C2DT30517H

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