Issue 2, 2012
From the journal:

Dalton Transactions

Complexation of novel diglycolamide functionalized calix[4]arenes: Unusual extraction behaviour, transport, and fluorescence studies†

Prasanta K. Mohapatra,*a   Mudassir Iqbal,b   Dhaval R. Raut,a   Willem Verboom,b   Jurriaan Huskensb  and  Shrikant V. Godbolea  

* Corresponding authors

a Radiochemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai, India
E-mail: mpatra@barc.gov.in
Fax: +91-22-25505151
Tel: +91-22-25594576

b Laboratory of Molecular Nanofabrication, MESA+ Institute for Nanotechnology, University of Twente, P.O. Box 217, Enschede, The Netherlands

Abstract

Three diglycolamide functionalized calix[4]arenes (calix[4]-nDGA) were synthesized and evaluated for their extraction behaviour towards lanthanide/actinide ions. Exceptionally high DAm and DPu values indicate these radiotoxic elements can be selectively removed from nuclear waste solutions. Transport and laser induced fluorescence studies indicated strong complexation of the trivalent metal ions with the calix[4]-4DGA ligand.

Graphical abstract: Complexation of novel diglycolamide functionalized calix[4]arenes: Unusual extraction behaviour, transport, and fluorescence studies

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C1DT11561H
Article type
Communication
Submitted
19 Aug 2011
Accepted
19 Oct 2011
First published
10 Nov 2011

Dalton Trans., 2012,41, 360-363

Permissions

Request permissions

Complexation of novel diglycolamide functionalized calix[4]arenes: Unusual extraction behaviour, transport, and fluorescence studies

P. K. Mohapatra, M. Iqbal, D. R. Raut, W. Verboom, J. Huskens and S. V. Godbole, Dalton Trans., 2012, 41, 360 DOI: 10.1039/C1DT11561H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements