Issue 44, 2006
From the journal:

Chemical Communications

An unprecedented heterotrimetallic Fe/Cu/Co core for mild and highly efficient catalytic oxidation of cycloalkanes by hydrogen peroxide†

Dmytro S. Nesterov,a   Volodymyr N. Kokozay,*a   Viktoriya V. Dyakonenko,b   Oleg V. Shishkin,b   Julia Jezierska,c   Andrew Ozarowski,d   Alexander M. Kirillov,e   Maximilian N. Kopyloviche  and  Armando J. L. Pombeiro*e  

* Corresponding authors

a Depart. Inorg. Chemistry, National Taras Shevchenko Univ., Volodymyrska str. 64, Kyiv, Ukraine
E-mail: kokozay@univ.kiev.ua
Fax: +38044 2862467

b STC “Institute for Single Crystals” Nat. Academy of Sciences of Ukraine, 60 Lenina ave., Kharkiv, Ukraine

c Faculty of Chemistry, Univ. of Wroclaw, 14 Joliot-Curie Str., Wroclaw, Poland

d Nat. High Magnetic Field Laboratory, Florida State Univ., 1800 E. Paul Dirac Drive, Tallahassee, Florida, USA

e Centro Química Estrutural, Complexo I, Instituto Sup. Técnico, Av. Rovisco Pais, Lisbon, Portugal
E-mail: pombeiro@ist.utl.pt
Fax: +351 218464455

Abstract

An unprecedented hexanuclear heterotrimetallic Fe/Cu/Co complex bearing two Cu(μ-O)2Co(μ-O)2Fe cores is easily prepared by self-assembly and acts as a remarkable catalyst for the peroxidative oxidation of cycloalkanes under mild conditions.

Graphical abstract: An unprecedented heterotrimetallic Fe/Cu/Co core for mild and highly efficient catalytic oxidation of cycloalkanes by hydrogen peroxide

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Article information

DOI
https://doi.org/10.1039/B608790F
Article type
Communication
Submitted
22 Jun 2006
Accepted
30 Aug 2006
First published
22 Sep 2006

Chem. Commun., 2006, 4605-4607

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An unprecedented heterotrimetallic Fe/Cu/Co core for mild and highly efficient catalytic oxidation of cycloalkanes by hydrogen peroxide

D. S. Nesterov, V. N. Kokozay, V. V. Dyakonenko, O. V. Shishkin, J. Jezierska, A. Ozarowski, A. M. Kirillov, M. N. Kopylovich and A. J. L. Pombeiro, Chem. Commun., 2006, 4605 DOI: 10.1039/B608790F

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