Issue 44, 2006
From the journal:

Chemical Communications

Photochemical asymmetric synthesis of phenyl-bearing quaternary chiral carbons using chiral-memory effect on β-hydrogen abstraction by thiocarbonyl group†

Masami Sakamoto,*a   Hiroya Kawanishi,a   Takashi Mino,a   Yoshio Kasashimaa  and  Tsutomu Fujitaa  

* Corresponding authors

a Department of Applied Chemistry and Biotechnology, Faculty of Engineering, Chiba University, Yayoi-cho, Inage-ku, Chiba, Japan
E-mail: sakamotom@faculty.chiba-u.jp
Fax: +81 43 290 3401
Tel: +81 43 290 3387

Abstract

Quaternary chiral carbons were effectively generated from tertiary chiral carbons via photochemical intramolecular β-hydrogen abstraction reaction of thioimides involving the highly-controlled chiral-memory effect.

Graphical abstract: Photochemical asymmetric synthesis of phenyl-bearing quaternary chiral carbons using chiral-memory effect on β-hydrogen abstraction by thiocarbonyl group

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Article information

DOI
https://doi.org/10.1039/B608513J
Article type
Communication
Submitted
16 Jun 2006
Accepted
30 Aug 2006
First published
25 Sep 2006

Chem. Commun., 2006, 4608-4610

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Photochemical asymmetric synthesis of phenyl-bearing quaternary chiral carbons using chiral-memory effect on β-hydrogen abstraction by thiocarbonyl group

M. Sakamoto, H. Kawanishi, T. Mino, Y. Kasashima and T. Fujita, Chem. Commun., 2006, 4608 DOI: 10.1039/B608513J

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