The second-order rate constants for reactions between an arene radical anion and 1-iodobutane have been obtained over a range of log(k/dm3 mol–1 s–1), from ca. 6 up to the bimolecular diffusion limit; a linear dependence of log k on E° for the donor radical anion is found and interpreted in a qualitative fashion.
J. Grimshaw, J. R. Langan and G. A. Salmon, J. Chem. Soc., Chem. Commun., 1988, 1115 DOI: 10.1039/C39880001115
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