Silver(III) metalloporphyrin complexes, AgIIIP [where P = octaethylporphyrin (1), meso-tetraphenylporphyrin (2), meso-tetra(2,4,6-trimethoxyphenyl)porphyrin (3)] were unexpectedly found to contain residual paramagnetism owing to the presence of AgIIP in small amounts; the possibility of generating molecular conductors and semiconductors, based on silver metalloporphyrin complexes, is examined.
L. R. Milgrom and C. C. Jones, J. Chem. Soc., Chem. Commun., 1988, 576 DOI: 10.1039/C39880000576
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