A new dinucleating macrocyclic ligand (5), possessing two ‘soft’ pyridyldithio chelating units held rigidly apart by a m-xylyl group, is readily synthesized; its crystal structure has been determined, and its dinuclear copper(II) complex shows moderate activity as a catalyst for alkene oxidation and phosphate hydrolysis.
C. A. Salata, D. Van Engen and C. J. Burrows, J. Chem. Soc., Chem. Commun., 1988, 579 DOI: 10.1039/C39880000579
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