Heteronuclear cluster compounds can be prepared from reactions between [M3(µ-H)(µ-COMe)(CO)10](M = Fe or Ru) and [ AuMePPh3], or between the tri-iron compound and [Pt(C2H4)2(PPh3)]; the structures of [AuRu3(µ2-COMe)(CO)10(PPh3)] and [Fe3Pt(µ3-H)(µ3-COMe)(CO)10(PPh3)] have been established by X-ray diffraction.
M. Green, K. A. Mead, R. M. Mills, I. D. Salter, F. G. A. Stone and P. Woodward, J. Chem. Soc., Chem. Commun., 1982, 51 DOI: 10.1039/C39820000051
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