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Issue 1, 1982
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Synthesis and X-ray analysis of the hydrido-carbido-monoanion [HOs10C(CO)24]; a cluster compound with an interstitial hydrogen ligand in a tetrahedral site

Abstract

Protonation of the carbido-dianion [Os10C(CO)24]2– with cone. H2SO4gives [HOs10C(Co)24] and H2Os10C(CO)24; from X-ray analyses of the [Ph4As]+ and [Ph3MeP]+ salts of the hydrido-monoanion, which show a structure with a close-packed carbonyl distribution virtually identical to that of the dianion, it may be deduced that this is the first example of an H-ligand in a tetrahedral site of a polynuclear carbonyl species.

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Article type: Paper
DOI: 10.1039/C39820000049
Citation: J. Chem. Soc., Chem. Commun., 1982, 49-51
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    Synthesis and X-ray analysis of the hydrido-carbido-monoanion [HOs10C(CO)24]; a cluster compound with an interstitial hydrogen ligand in a tetrahedral site

    P. F. Jackson, B. F. G. Johnson, J. Lewis, M. McPartiln and W. J. H. Nelson, J. Chem. Soc., Chem. Commun., 1982, 49
    DOI: 10.1039/C39820000049

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