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Cp*Co(III)-catalyzed ortho-amidation of azobenzenes with dioxazolones

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Abstract

Cp*Co(III)-catalyzed C–H amidation of azobenzene with dioxazolones has been developed. The amidation reaction does not require external oxidants and gives carbon dioxide as the only by-product. Both symmetrical and unsymmetrical azobenzenes were found to undergo amidation smoothly with broad functional group tolerance.

Graphical abstract: Cp*Co(iii)-catalyzed ortho-amidation of azobenzenes with dioxazolones

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Publication details

The article was received on 03 Mar 2017, accepted on 06 Apr 2017 and first published on 06 Apr 2017


Article type: Communication
DOI: 10.1039/C7OB00540G
Citation: Org. Biomol. Chem., 2017, Advance Article
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    Cp*Co(III)-catalyzed ortho-amidation of azobenzenes with dioxazolones

    G. Borah, P. Borah and P. Patel, Org. Biomol. Chem., 2017, Advance Article , DOI: 10.1039/C7OB00540G

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