Jump to main content
Jump to site search

Issue 40, 2017
Previous Article Next Article

Achiral aromatic solvent-induced assembly of 3-D homochiral porous 3d–4f heterometallic-organic frameworks based on isonicotinic acid

Author affiliations

Abstract

Via induction of achiral aromatic solvents, two 3-D monochiral 3d–4f MOFs (1 and 2) from the ligand HIN without any chiral auxiliary are uncommonly constructed. The results show that the homochiral compounds 1 and 2 are enantiopure rather than exhibiting enantiomeric excess. Obviously, this work has brought major synthetic advancement in homochiral framework materials of great significance.

Graphical abstract: Achiral aromatic solvent-induced assembly of 3-D homochiral porous 3d–4f heterometallic-organic frameworks based on isonicotinic acid

Back to tab navigation

Supplementary files

Publication details

The article was received on 31 Aug 2017, accepted on 13 Sep 2017 and first published on 13 Sep 2017


Article type: Communication
DOI: 10.1039/C7CE01580A
Citation: CrystEngComm, 2017,19, 5956-5959
  •   Request permissions

    Achiral aromatic solvent-induced assembly of 3-D homochiral porous 3d–4f heterometallic-organic frameworks based on isonicotinic acid

    H. Jin, X. Hong, H. Tan, Q. Wei, X. Lin and Y. Cai, CrystEngComm, 2017, 19, 5956
    DOI: 10.1039/C7CE01580A

Search articles by author

Spotlight

Advertisements