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Achiral aromatic solvent-induced assemblies of the 3-D homochiral porous 3d-4f heterometallic-organic frameworks based on isonicotinic acid

Abstract

Via induction of achiral aromatic solvents, two 3-D monochiral 3d-4f MOFs (1 and 2) from the ligand HIN without any chiral auxiliary are uncommonly constructed. And the results show homochirality of 1-2 are enantiopurity rather than enantiomeric excess. Obviously, this work has brought major synthetic advance for homochiral framework materials with the important significance.

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Publication details

The article was received on 31 Aug 2017, accepted on 13 Sep 2017 and first published on 13 Sep 2017


Article type: Communication
DOI: 10.1039/C7CE01580A
Citation: CrystEngComm, 2017, Accepted Manuscript
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    Achiral aromatic solvent-induced assemblies of the 3-D homochiral porous 3d-4f heterometallic-organic frameworks based on isonicotinic acid

    H. Jin, X. Hong, H. Tan, W. Qin, X. Lin and Y. Cai, CrystEngComm, 2017, Accepted Manuscript , DOI: 10.1039/C7CE01580A

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