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Issue 82, 2017
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Inclusion of a dithiadiazolyl radical in a seemingly non-porous solid

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Abstract

Inclusion of the dithiadiazolyl radical PhCNSSN˙ into the dynamically porous metallocycle [Cu2(L1)2Cl4], where L1 is the bidentate ligand 1,3-bis(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene, has been achieved by gas phase diffusion. Single crystal X-ray diffraction, powder X-ray diffraction, UV-visible spectroscopy, EPR and SQUID magnetometry studies confirm inclusion of the radical into this seemingly non-porous material, and illustrate the antiferromagnetic coupling between the paramagnetic host and guest species. The radical guest is readily released by heating or by the addition of solvent (CH2Cl2).

Graphical abstract: Inclusion of a dithiadiazolyl radical in a seemingly non-porous solid

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Publication details

The article was received on 25 Aug 2017, accepted on 21 Sep 2017 and first published on 29 Sep 2017


Article type: Communication
DOI: 10.1039/C7CC06678C
Citation: Chem. Commun., 2017,53, 11310-11313
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    Inclusion of a dithiadiazolyl radical in a seemingly non-porous solid

    V. I. Nikolayenko, L. J. Barbour, A. Arauzo, J. Campo, J. M. Rawson and D. A. Haynes, Chem. Commun., 2017, 53, 11310
    DOI: 10.1039/C7CC06678C

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