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Issue 82, 2017
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[Hyp-Au-Sn9(Hyp)3-Au-Sn9(Hyp)3-Au-Hyp]: the longest intermetalloid chain compound of tin

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Abstract

The reaction of the metalloid tin cluster [Sn10(Hyp)4]2− with (Ph3P)Au-SHyp (Hyp = Si(SiMe3)3) gave an intermetalloid cluster [Au3Sn18(Hyp)8]1, which is the longest intermetalloid chain compound of tin to date. 1 shows a structural resemblance to binary AuSn phases, which is expected for intermetalloid clusters.

Graphical abstract: [Hyp-Au-Sn9(Hyp)3-Au-Sn9(Hyp)3-Au-Hyp]−: the longest intermetalloid chain compound of tin

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Publication details

The article was received on 07 Sep 2017, accepted on 23 Sep 2017 and first published on 25 Sep 2017


Article type: Communication
DOI: 10.1039/C7CC07029B
Citation: Chem. Commun., 2017,53, 11314-11317
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    [Hyp-Au-Sn9(Hyp)3-Au-Sn9(Hyp)3-Au-Hyp]: the longest intermetalloid chain compound of tin

    M. Binder, C. Schrenk, T. Block, R. Pöttgen and A. Schnepf, Chem. Commun., 2017, 53, 11314
    DOI: 10.1039/C7CC07029B

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