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A new synthetic route to in-chain metallopolymers via copper(I) catalyzed azide–platinum–acetylide iClick

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Abstract

The first example of an in-chain metallo-poly(triazolate) synthesized by CuAAC is reported. Azido–platinum–acetylide (A–M–B) monomers are catalytically polymerized with copper(I) acetate to yield 1,2,3-triazolate linked Pt(II) units. The metallopolymers are characterized by multinuclear NMR, IR, UV/Vis, GPC, and MS.

Graphical abstract: A new synthetic route to in-chain metallopolymers via copper(i) catalyzed azide–platinum–acetylide iClick

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Publication details

The article was received on 10 Aug 2017, accepted on 11 Aug 2017 and first published on 11 Aug 2017


Article type: Communication
DOI: 10.1039/C7CC06289C
Citation: Chem. Commun., 2017, Advance Article
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    A new synthetic route to in-chain metallopolymers via copper(I) catalyzed azide–platinum–acetylide iClick

    C. C. Beto, E. D. Holt, Y. Yang, I. Ghiviriga, K. S. Schanze and A. S. Veige, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC06289C

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