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A New Synthetic Route to In-Chain Metallopolymers via Copper(I) Catalyzed Azide-Platinum-Acetylide iClick

Abstract

The first example of an in-chain metallo-poly(triazolate) synthesized by CuAAC is reported. Azido-platinum-acetylide (A-M-B) monomers are catalytically polymerized with copper(I) acetate to yield 1,2,3-triazolate linked Pt(II) units. The metallopolymers are characterized by multinuclear NMR, IR, UV/Vis, GPC, and MS.

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Publication details

The article was accepted on 11 Aug 2017 and first published on 11 Aug 2017


Article type: Communication
DOI: 10.1039/C7CC06289C
Citation: Chem. Commun., 2017, Accepted Manuscript
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    A New Synthetic Route to In-Chain Metallopolymers via Copper(I) Catalyzed Azide-Platinum-Acetylide iClick

    C. C. Beto, E. D. Holt, Y. Yang, I. Ghiviriga, K. S. Schanze and A. S. Veige, Chem. Commun., 2017, Accepted Manuscript , DOI: 10.1039/C7CC06289C

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