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Issue 71, 2017
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A kinetic study of mechanochemical halogen bond formation by in situ31P solid-state NMR spectroscopy

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Abstract

In situ 31P solid-state NMR studies of halogen bond formation between triphenylphosphine oxide and para-diiodotetrafluorobenzene provide insights into the cocrystallisation process and provide an estimate of the activation energy. The effects of temperature, magic-angle spinning speed, and initially added liquid on the reaction rate and mechanism have been investigated.

Graphical abstract: A kinetic study of mechanochemical halogen bond formation by in situ31P solid-state NMR spectroscopy

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Publication details

The article was received on 29 Jun 2017, accepted on 14 Aug 2017 and first published on 14 Aug 2017


Article type: Communication
DOI: 10.1039/C7CC05051H
Citation: Chem. Commun., 2017,53, 9930-9933
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    A kinetic study of mechanochemical halogen bond formation by in situ31P solid-state NMR spectroscopy

    Y. Xu, L. Champion, B. Gabidullin and D. L. Bryce, Chem. Commun., 2017, 53, 9930
    DOI: 10.1039/C7CC05051H

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