In situ 31P solid-state NMR studies of halogen bond formation between triphenylphosphine oxide and para-diiodotetrafluorobenzene provide insights into the cocrystallisation process and provide an estimate of the activation energy. The effects of temperature, magic-angle spinning speed, and initially added liquid on the reaction rate and mechanism have been investigated.
The article was received on 29 Jun 2017, accepted on 14 Aug 2017 and first published on 14 Aug 2017
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