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Issue 1, 2017
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Highly selective olefin-assisted palladium-catalyzed oxidative carbocyclization via remote olefin insertion

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Abstract

A highly selective olefin-assisted palladium-catalyzed oxidative carbocyclization via remote olefin insertion to afford cyclohexenes has been developed. It was shown that the assisting olefin moiety was indispensable for the formation of the cyclohexene product. Furthermore, preliminary studies on chiral anion-induced asymmetrical carbocyclization–borylation of enallenes have been carried out.

Graphical abstract: Highly selective olefin-assisted palladium-catalyzed oxidative carbocyclization via remote olefin insertion

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Publication details

The article was received on 17 Jun 2016, accepted on 01 Sep 2016 and first published on 02 Sep 2016


Article type: Edge Article
DOI: 10.1039/C6SC02660E
Citation: Chem. Sci., 2017,8, 616-620
  • Open access: Creative Commons BY license
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    Highly selective olefin-assisted palladium-catalyzed oxidative carbocyclization via remote olefin insertion

    Y. Qiu, B. Yang, C. Zhu and Jan-E. Bäckvall, Chem. Sci., 2017, 8, 616
    DOI: 10.1039/C6SC02660E

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