On the association of neutral and cationic tris(tetrathiafulvaleno)dodecadehydro[18]annulenes

Christian R. Parker; Kasper Lincke; Mikkel A. Christensen; Karol Lušpai; Peter Rapta; Thomas Just Sørensen; Thorbjørn J. Morsing; Lin Du; Henrik G. Kjaergaard; Ole Hammerich; François Diederich; Mogens Brøndsted Nielsen

doi:10.1039/C5OB02087E

On the association of neutral and cationic tris(tetrathiafulvaleno)dodecadehydro[18]annulenes†

Christian R. Parker,^a Kasper Lincke,^ab Mikkel A. Christensen,^a Karol Lušpai,^c Peter Rapta,^c Thomas Just Sørensen,^a Thorbjørn J. Morsing,^a Lin Du,^a Henrik G. Kjaergaard,^a Ole Hammerich,^a François Diederich^b and Mogens Brøndsted Nielsen*^a

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^a Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen Ø, Denmark
E-mail: mbn@chem.ku.dk

^b Laboratorium für Organische Chemie, ETH Zürich, Hönggerberg, HCI, Wolfgang-Pauli-Strasse 10, CH-8093 Zürich, Switzerland

^c Institute of Physical Chemistry and Chemical Physics, Faculty of Chemical and Food Technology, Slovak University of Technology, Radlinskeho 9, SK-81237 Bratislava, Slovak Republic

Abstract

Here, we report the first X-ray crystal structure of a tetrathiafulvalene-fused dehydroannulene with peripheral ethylthio substituents. In addition, we have subjected this compound to electrochemical and UV-Vis-NIR/ESR spectroelectrochemical studies to elucidate the degree to which the oxidised species associate.

Organic & Biomolecular Chemistry

On the association of neutral and cationic tris(tetrathiafulvaleno)dodecadehydro[18]annulenes†

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On the association of neutral and cationic tris(tetrathiafulvaleno)dodecadehydro[18]annulenes

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