Issue 7, 2016
From the journal:

New Journal of Chemistry

Room temperature hydroamination of alkynes with anilines catalyzed by anti-Bredt di(amino)carbene gold(i) complexes†

Xingbang Hu,‡a   David Martin ORCID logo *ab  and  Guy Bertrand*a  

* Corresponding authors

a UCSD-CNRS Joint Research Laboratory (UMI 3555), Department of Chemistry and Biochemistry, University of California, San DiegoLa Jolla, California 92093-0343, USA
E-mail: guybertrand@ucsd.edu

b UMR CNRS 5250, Département de Chimie Moléculaire, Université Joseph Fourier B. P. 53, 38041 Cedex 9 Grenoble, France
E-mail: david.martin@univ-grenoble-alpes.fr

Abstract

The room temperature hydroamination of alkynes with phenylhydrazine and anilines was achieved with an anti-Bredt di(amino) carbene gold(I) chloride as precatalyst, in the presence of KBArF as chloride scavenger. These reactions were highly regioselective and excellent conversions were obtained (up to 99%) for a series of alkynes and anilines.

Graphical abstract: Room temperature hydroamination of alkynes with anilines catalyzed by anti-Bredt di(amino)carbene gold(i) complexes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C6NJ00980H
Article type
Letter
Submitted
29 Mar 2016
Accepted
10 May 2016
First published
11 May 2016

New J. Chem., 2016,40, 5993-5996

Permissions

Request permissions

Room temperature hydroamination of alkynes with anilines catalyzed by anti-Bredt di(amino)carbene gold(I) complexes

X. Hu, D. Martin and G. Bertrand, New J. Chem., 2016, 40, 5993 DOI: 10.1039/C6NJ00980H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements