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Issue 43, 2016
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A series of robust metal–porphyrinic frameworks based on rare earth clusters and their application in N–H carbene insertion

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Abstract

We herein report a series of microporous metal–porphyrinic frameworks (MPFs), denoted as NUPF-2M, based on rare earth (RE) clusters. NUPF-2M represent the first examples of RE cluster-based MPFs, possessing a rarely seen shp-a topology and exhibiting high thermal and thermal stabilities. After a post-metallization process with FeCl3, NUPF-2M is catalytically active as an efficient heterogeneous catalyst for intermolecular N–H carbene insertion.

Graphical abstract: A series of robust metal–porphyrinic frameworks based on rare earth clusters and their application in N–H carbene insertion

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Publication details

The article was received on 22 Sep 2016, accepted on 13 Oct 2016 and first published on 14 Oct 2016


Article type: Communication
DOI: 10.1039/C6DT03678C
Citation: Dalton Trans., 2016,45, 17108-17112
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    A series of robust metal–porphyrinic frameworks based on rare earth clusters and their application in N–H carbene insertion

    L. Xu, M. Zhai, F. Wang, L. Sun and H. Du, Dalton Trans., 2016, 45, 17108
    DOI: 10.1039/C6DT03678C

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