Issue 43, 2016
From the journal:

Dalton Transactions

Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex†

Rong-Jia Wei, ORCID logo a   Ryohei Nakahara,a   Jamie M. Cameron, ORCID logo a   Graham N. Newton,ab   Takuya Shiga,a   Hajime Sagayama,c   Reiji Kumai,c   Youichi Murakamic  and  Hiroki Oshio ORCID logo *a  

* Corresponding authors

a Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba 305-8571, Japan
E-mail: oshio@chem.tsukuba.ac.jp
Fax: +81-29-853-4238
Tel: +81-29-853-4238

b School of Chemistry, The University of Nottingham, University Park, Nottingham, UK

c Photon Factory and Condensed Matter Research Center, Institute of Materials Structure Science, High Energy Accelerator Research Organization (KEK), Tsukuba 305-0801, Japan

Abstract

A cyanide-bridged [Co3Fe2] cluster with trigonal bipyramidal geometry shows solvent-driven reversible on/off switching of its thermally induced electron-transfer-coupled spin transition (ETCST) behaviour.

Graphical abstract: Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex

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Article information

DOI
https://doi.org/10.1039/C6DT03416K
Article type
Communication
Submitted
01 Sep 2016
Accepted
12 Oct 2016
First published
19 Oct 2016

Dalton Trans., 2016,45, 17104-17107

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Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex

R. Wei, R. Nakahara, J. M. Cameron, G. N. Newton, T. Shiga, H. Sagayama, R. Kumai, Y. Murakami and H. Oshio, Dalton Trans., 2016, 45, 17104 DOI: 10.1039/C6DT03416K

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