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Issue 45, 2016
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Tuning the electronic structure of thiolate-protected 25-atom clusters by co-substitution with metals having different preferential sites

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Abstract

Trimetallic Au24−xAgxPd and tetrametallic Au24−xyAgxCuyPd clusters were synthesized by the subsequential metal exchange reactions of dodecanethiolate-protected Au24Pd clusters. EXAFS measurements revealed that Pd, Ag, and Cu dopants preferentially occupy the center and edge sites of the core, and staple sites, respectively. Spectroscopic and theoretical studies demonstrated that the synergistic effects of multiple substitutions on the electronic structures are additive in nature.

Graphical abstract: Tuning the electronic structure of thiolate-protected 25-atom clusters by co-substitution with metals having different preferential sites

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Publication details

The article was received on 13 Aug 2016, accepted on 18 Aug 2016 and first published on 18 Aug 2016


Article type: Communication
DOI: 10.1039/C6DT03214A
Citation: Dalton Trans., 2016,45, 18064-18068
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    Tuning the electronic structure of thiolate-protected 25-atom clusters by co-substitution with metals having different preferential sites

    S. Sharma, S. Yamazoe, T. Ono, W. Kurashige, Y. Niihori, K. Nobusada, T. Tsukuda and Y. Negishi, Dalton Trans., 2016, 45, 18064
    DOI: 10.1039/C6DT03214A

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