Issue 20, 2016
From the journal:

Chemical Communications

Unprecedented W2(0) quadruply bonded complex supported by π-donor ligands†

K. Ventura,a   J. R. Prat,a   L. M. Aguirre Quintana,a   A. Goosa  and  D. Villagran*a  

* Corresponding authors

a Department of Chemistry, The University of Texas at El Paso, El Paso TX, USA
E-mail: dino@utep.edu

Abstract

A quadruply bonded complex W2(DippF)2K2 with a W2(0) core was synthesized and structurally characterized. The observed W–W distance of 2.407(1) Å and DFT calculations are consistent to the unprecedented electronic structure in D2h symmetry of σ2π2π2δ2 δ2δ*2 where the HOMO is the δ* orbital.

Graphical abstract: Unprecedented W2(0) quadruply bonded complex supported by π-donor ligands

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Article information

DOI
https://doi.org/10.1039/C5CC09972B
Article type
Communication
Submitted
04 Dec 2015
Accepted
11 Feb 2016
First published
12 Feb 2016

Chem. Commun., 2016,52, 3974-3976

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Unprecedented W2(0) quadruply bonded complex supported by π-donor ligands

K. Ventura, J. R. Prat, L. M. Aguirre Quintana, A. Goos and D. Villagran, Chem. Commun., 2016, 52, 3974 DOI: 10.1039/C5CC09972B

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