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Issue 8, 2016
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A water-soluble metal–organic complex array as a multinuclear heterometallic peptide amphiphile that shows unconventional anion dependency in its self-assembly

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Abstract

Water-soluble metal–organic complex array 1, bearing Ru(II), Pt(II) and Rh(III) complexes at the side residues of the short peptide, exhibits anion and pH-responsive self-assembly behaviours in aqueous media. NaCl-induced aggregation of 1 at neutral pH was suppressed in phosphate buffered saline containing a mixture of Cl, HPO42− and H2PO4, which is unconventional for a peptide amphiphile.

Graphical abstract: A water-soluble metal–organic complex array as a multinuclear heterometallic peptide amphiphile that shows unconventional anion dependency in its self-assembly

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Publication details

The article was received on 29 Oct 2015, accepted on 02 Nov 2015 and first published on 02 Nov 2015


Article type: Communication
DOI: 10.1039/C5CC08973E
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2016,52, 1579-1581
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    A water-soluble metal–organic complex array as a multinuclear heterometallic peptide amphiphile that shows unconventional anion dependency in its self-assembly

    P. K. Sukul, P. Bose, T. Takei, O. M. Yaghi, Y. He, M. Lee and K. Tashiro, Chem. Commun., 2016, 52, 1579
    DOI: 10.1039/C5CC08973E

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